Carrie Underwood and Vince Gill’s powerful duet of “How Great Thou Art” remains one of the most moving moments in country music.

Both proud Oklahoma natives and esteemed Grand Ole Opry members, Carrie Underwood and Vince Gill have joined forces on numerous occasions—and each time they deliver something remarkable. Yet their 2011 rendition of the time-honored hymn “How Great Thou Art” stands out as perhaps their finest joint performance to date.

Audiences and critics alike still point to this duet when asked to name the greatest collaboration in country music history. The setting was the ACM’s Girls’ Night Out: Superstar Women of Country special, where Underwood began by honoring her fellow female artists before turning to Gill.

“Thank you so much for sharing this very special night with me—it truly means the world,” she expressed, her gratitude setting the stage for what followed.

From the first gentle notes, Underwood’s voice floated over the melody while Gill accompanied her on guitar. As the hymn progressed, her vocals swelled with increasing passion until Gill stepped in, weaving in rich, resonant harmonies that elevated the song to new heights.

Midway through, Gill offered Underwood the spotlight to catch her breath, treating the audience to a stirring guitar solo. When she rejoined, her delivery brimmed with heartfelt intensity, each line more spine-tingling than the last.

The crowd responded in kind—rising to their feet, thunderous applause erupting long before the final chord. Many in attendance were visibly moved, tears glistening as they witnessed such a seamless fusion of talent and emotion.

Even now, more than a decade later, listening to this performance can bring tears to the eyes of anyone who appreciates genuine musical artistry. Experience it for yourself below.

It’s no wonder fans continue to revisit Carrie Underwood and Vince Gill’s unforgettable “How Great Thou Art” performance over ten years later—its blend of heartfelt vocals, masterful instrumentation, and pure emotion has secured its place in country music lore.

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